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oscillations of infinitesimal amplitude and a consequent dissipative effect However, one may imagine a process wherein small mass increments are removed one after another at a rate such that the piston's rise is continuous, with minute oscillation only at the end of the process The limiting case of removal of a succession of infinitesimal masses from the piston is approximated when the masses m in Fig 22 are replaced by a pile of powder, blown in a very fine stream from the piston During this process, the piston rises at a uniform but very slow rate, and the powder collects in storage at ever higher levels The system is never more than differentially displaced from internal equilibrium or from equilibrium with its surroundings If the removal of powder from the piston is stopped and the direction of transfer of powder is reversed, the process reverses direction and proceeds backwards along its original path Both the system and its surroundings are ultimately restored to their initial conditions The original process is reversible Without the assumption of a frictionless piston, we cannot imagine a reversible process If the piston sticks because of friction, a finite mass must be removed before the piston breaks free Thus the equilibrium condition necessary to reversibility is not maintained Moreover, friction between two sliding parts is a mechanism for the dissipation of mechanical energy into internal energy This discussion has centered on a single closed-system process, the expansion of a gas in a cylinder The opposite process, compression of a gas in a cylinder, is described in exactly the same way There are, however, many processes which are driven by the imbalance of forces other than mechanical forces For example, heat flow occurs when a temperature difference exists, electricity flows under the influence of an electromotive force, and chemical reactions occur because a chemical potential exists In general, a process is reversible when the net force driving it is only differential in size Thus heat is transferred reversibly when it flows from a finite object at temperature T to another such object at temperature T - d T.

11:

(1183)

.

Figure 19-2. Three string values for the TEXT block For value A, the text I entered is I , with no spaces. Value B contains am (with a leading space), and value C is SPOT (with a leading space). The leading spaces will keep the combined text from looking like IamSPOT ; instead, the combined text will look like I am SPOT when displayed on the screen. Once the text items are combined, how do I display the new string on the screen I ll first add in a DISPLAY block to show the text on the screen (see Figure 19-3). I drag a wire from the output Text data plug (of the TEXT block) into the input Text data plug (on the DISPLAY block). The output Text data plug provides the combined text from A, B, and C.

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which follows from Eq (1182) and Eq (63), the definition of G The definition of M E is analogous to the definition of a residual property as given by Eq (641) Indeed, excess properties have a simple relation to residual properties, found by subtracting Eq (641) from Eq (1182):

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